@dolgarrenan,
If thats the case then it
may suggest that Asus have indeed implemented some sort of BIOS lockout when Windows 10 is installed in UEFI mode (IE: on a GUID formatted partition) and requires you to enter the BIOS via the Windows 10 procedure rather than through the post boot key shortcut.
This behaviour also reminds me of Windows "Fast Startup" feature which is known to disable post boot entry to the BIOS.
Check to see if you have the Windows "Fast Startup" feature enabled .. if it is disable it :-
Windows 10's Fast Startup (called Fast Boot in Windows 8) works similarly to the hybrid sleep mode of previous versions of Windows.
www.howtogeek.com
Quote from the guide linked above :-
Cheers
Jay