Of course you can!
Download macOS Catalina 10.15.6
Follow
this apple page to create a bootable USB installer for Catalina
Download the
attached EFI folder created by Casey
Customize your config.plist (from downloaded EFI folder) as you need (follow
the guide, everything is well explained)
Mount EFI partition of your Catalina USB installer
Copy and past downloaded EFI folder with your custom config.plist inside the EFI partition of your Catalina USB installer
Boot your PC from Catalina USB installer
Install Catalina