Well look at the bright side -- you are well within your return window for the new motherboard!
Regarding iMac19,2 -- if your USB ports are working then certainly no need to change the SMBIOS.
- You have Vt-d enabled -- it should be disabled.
- You config.plist does not have dart=0, which is a guard against the ill effects of Vt-d being enabled.
- You also have two memory fix drivers in drivers64UEFI, but only 1 is allowed at a time.
- You are using SMBIOS iMac19,2 which is incompatible with USBInjectAll.kext. Please try iMac19,1 or iMac18,3.
- In your Kernel and Kext Patches section, there is no External Icons Patch. This will affect sleep/wake when external disks are connection.
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External Icons Patch? tell me more of this. Could it effect my sleep/wake issues? I have an external drive connected. It appears on the desktop as external (orange). Nothing like it in Kernel and Kext Patches.
I added it, though I don't have issues with sleep/wake, in hopes that other adverse effects would "chill." I'll pull it today and see if there's a difference. My culprit was using duplicate fixdrv's