I recently update my old workstation directly form Catalina to Big Sur from and Clover to OpenCore.
This is the link it helps me.
https://github.com/b00t0x/Z9PE-D8_WS_Hackintosh
I didn't flashed the motherboard with the custom rom, so I have to remove from the ACPI folder:
- SSDT-CPU-OC.aml
-...
VINTAGE
Asus Z9PE-D8 WS / 2x Intel Xeon E5 2687w Catalina / 64bg 1600mhz DDR3
I know it's an oldie but I manage to install Catalina with the Radeon 560 4go at the #5 pci-e line (still this problem)
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