I got an Apollo Twin Duo today, I have a GA Z77MX-D3H-TH v1.1 and running it on 10.9.2 flawlessy so far, actually everything works fine on this mobo from PM to sleep USB3 front back hot swap etc etc
I also followed Toleda guide on native PM on Maverick.
I just set in the bios Wake from thunderbolt device - disable... it didn't worked at first but then I remembered I updated bios and so I checked, it was enabled again... rebooted and Apollo connected on the fly!
Just one thing, sound preference says Apollo PCI while in System profiler says no thunderbolt device nor PCI card installed... anyway it works so I'm fine with that