I’ve already selected the first option and returned to Amazon my PCI SATA Card and placed an order for a Syba SI-PEX40064 4 Port that runs a Marvel 88se9215 controller.
It will arrive next week and I’ll let you know.
Problem resolved!
We can update the first post with this PCI SATA card from MZHOU, so anyone that wants to add two more SATA ports to their hackintoshes avoid it. It works perfectly with Windows, but macOS recognize the two ports and only connects with one drive.
Code:
https://www.amazon.es/gp/product/B099ZCXJLQ/
I returned the card to Amazon, ordered a Syba SI-PEX40064 4 Port SATA III PCI-e 2.0 card and received an IOCrest PCI Express card based on Marvell 9215 chip that works flawlessly either in Windows or the latest macOS Monterey RC I'm running.
Though is not labelled as Syba, the part number on the back is exactly the one I've ordered SI-PEX40064.
In Windows 11 Pro, the PCI Express card is detected as a Marvell 88SE9215 SATA 6Gb/s controller
And macOS reports the 4 new SATA ports under Generic AHCI controllers, but this is only cosmetics as it works perfectly.
I've connected 2 drives to the #3 (10TB WD Red) and #4 (120GB Kingston SSD) connectors of the card because I can handle the cabling in a better way.
The 10TB Western Digital Red hard drive performance is top-notch under Windows, with more than 200MB/s sequential read and write speed, fantastic for a mechanical - not SSD - drive.
Under macOS Monterey the speed is equivalent.
The issue is closed and I'm ready to migrate data to the new hard drive with confidence.